Comfort design and optimization of direct expansion multi-connected radiant air conditioning based on 3D flow field simulation

The air conditioning method based on radiation heat exchange has the characteristics of small vertical temperature gradient, high thermal comfort and energy saving, and has become a hot spot of attention. The Fluent numerical simulation, the experiment in this paper studies the direct expansion multi-line radiant air conditioner under the artificially simulated climate environment in winter heating, summer cooling and dehumidification. The temperature difference of the radiation + fresh air mode at the same time indoors under heating conditions is less than 2.5 °C, and the time to reach the indoor set temperature of 24 °C is about 2–3 h. Under cooling conditions, the temperature difference of the radiation + fresh air mode at the same time in the room is about 0.5–2 °C, and the time to reach the indoor set temperature of 26 °C is about 1–3 h. In the fresh air mode, the indoor temperature difference and response time at the same time are slightly larger than the radiation + fresh air mode. The freezing and dehumidification effect of fresh air is obvious, the moisture content of dehumidifying fresh air is between 6.3 and 10.5 g/kg, and the dehumidification efficiency can reach 50%. Under the same artificial simulated climate environment, the consumption of the three modes is not much different. When the outdoor temperature in heating conditions is higher than 9 °C, the fresh air mode can get better, and the radiation + fresh air mode can achieve better comfort when running indoors under various conditions.     

A zirconium-free glaze system for sanitary ceramics with SiO2-CaCO3-TiO2 composite opacifier containing anatase: Effect of interface combination among SiO2, CaCO3 and TiO2

TiO₂ is an ideal substitute to ZrSiO₄ ceramic opacifier, yet it is limited to application because of the undesirable yellowing resulting from rutile formation. Herein, the SiO₂-CaCO₃-TiO₂ composite opacifier (Si-Ca-Ti) was constructed. The glaze used Si-Ca-Ti presents a superior opacification performance than ZrSiO₄ opacified glaze without causing yellowing, showing L*, a*, b* values of 94.81, -0.67 and 3.23. By comparison, the glaze using SiO₂, CaCO₃, and TiO₂ mixture shows lower opacification and yellowish surface with L* and b* values of 92.99 and 5.36. It is revealed that there is a close interface bonding among SiO₂, CaCO₃ and TiO₂ in Si-Ca-Ti, which promotes their combination reaction to generate opacification phase titanite and inhibit rutile formation when sintering, resulting in the white surface and opacification improvement of the glaze. This study proposes a green and efficient strategy to achieve white and highly opacified glaze for sanitary ceramics, exhibiting good application prospect.     

Modeling the effects of loading scenario and thermal expansion coefficient on potential failure of cryo-compressed hydrogen vessels

A multiscale thermomechanical model for a simplified Type-3 cryogenic, compressed-hydrogen (H₂) storage vessel is described in this paper. The model accounts for the temperature-dependent elastic-plastic behavior of the vessel's carbon/epoxy composite overwrap and aluminum alloy liner. The homogenized thermo-elastic-plastic behavior for the individual laminae of the vessel layup is obtained using an incremental Eshelby-Mori-Tanaka approach associated with a micromechanical failure criterion to predict laminar failure while a standard elastic-plastic constitutive model is used to describe the behavior of the typical aluminum alloy assumed for the liner. The vessel's response to external loadings is modeled using a finite element method. Four loading scenarios, representing four thermomechanical cycles applied to the vessel, are analyzed to evaluate constituent and laminar stresses as well as the associated failure criterion during the cycle according to these scenarios. The model can provide helpful guidance to mitigate thermal stresses by selecting a suitable loading scenario, optimizing the layup, and tailoring the thermomechanical properties of the resin matrix.     

Sub-surface stress measurement of cross welds in a dissimilar welded pressure vessel

Manufacturing process of pressure vessels used in high-temperature applications normally needs employing dissimilar metal welds (DMWs) between austenitic and ferritic steel. However, high amount of thermal stresses at the welds are induced due to differences in coefficient of thermal expansion between the types of steel. This study investigates the evaluation of welding residual stresses in a pressure vessel manufactured by DMW of 316 L stainless steel shell to A106 carbon steel caps as well as similar welding of stainless steel shells. By using longitudinal critically refracted (LCR) ultrasonic waves, the residual stresses are experimentally measured. The ultrasonic method is based on acoustoelasticity law by which the ultrasonic wave velocity could be connected to the material stress. By changing the frequency in which the ultrasonic transducers are working, the LCR waves are able to penetrate in various depths of the material in order to measure the sub-surface residual stresses. Hence, four main aspects are considered in this study: (I) stress evaluation of the DMW; (II) sub-surface stress measurement; (III) stress evaluation of longitudinal weld and (IV) stress measurement in cross weld. It is demonstrated that the residual stresses of the DMW pressure vessel could be comprehensively evaluated by using the LCR method.     

Mechanism of mid-spatial-frequency waviness removal by viscoelastic polishing tool

Nanoscale roughness with ultra-precise form control can be readily achieved using compliant finishing methods such as bonnet polishing. However, their weak point lies in the difficulty of removing mid-spatial-frequency (MSF) waviness in the typical range from 0.1 to 5.0 mm wavelength. To overcome this shortcoming, a bonnet tool filled with viscoelastic fluid is developed and a comprehensive model is established to disclose its distinct removal behavior in the MSF range. The model considers tool viscoelasticity, stress distribution and workpiece topography. Experiments show high consistency with theoretical predictions, and show that MSF waviness can be effectively reduced using the proposed method.     

Refractive index of soft contact lens materials measured in packaging solution and standard phosphate buffered saline and the effect on back vertex power calculation

PurposeTo measure the refractive index (RI) of commonly available soft contact lens (CL) materials, their packaging solutions and compare to the manufacturers’ nominal RI. The relationship between RI versus water content, and the effect of inaccurate RI when converting lens power measured in solution to in-air back vertex power were examined.MethodsThe RI of 18 single vision soft CL materials were measured using CLR 12–70 digital refractometer. Three lenses of each material were measured, in their packaging solution and then after soaking in standard phosphate buffered saline (PBS). The RIs of packaging solution were also measured. Accuracy requirements for correct wet to dry power conversion based on thick lens formula were projected.ResultsThe standard deviation between three samples was less than 0.005. The measured RI ranged from 1.3744 ± 0.001–1.4265 ± 0.0004 for PBS soaked and from 1.3739 ± 0.0003–1.4264 ± 0.0024 for packaging solution soaked materials. Comparing nominal with mean measured PBS and packaging solution RIs, 5 and 3 lens materials, respectively, fell outside ISO tolerance. The packaging solution RI of DailiesAquaComfortPlus had the largest difference of 0.0040, compared to RI of standard PBS. For converting lens power measured in PBS to in-air power, the difference between measured and nominal RI of 0.0104 would result in wrongly calculated in-air power 0.99 D for a -6.00 D lens.ConclusionThe CLR 12–70 is reliable and accurate refractometer for the measurement of soft CL materials. Accurate RI measurements are of relevance with increased use of wavefront sensors to measure lens power while they are immersed in solution. Even small errors in solution or material RI can lead to significant errors in converted in-air power. To obtain valid in-air lens power results, measurement conditions must match the material and solution RIs used for the conversion.     

The impact of hydrogen addition to natural gas on flame stability

Injecting hydrogen into existing natural gas networks is a promising step to mitigate global warming. However there is little evidence showing that how much degree of hydrogen admixture can be accepted. Experiments on populations of gas appliances are not available at present, thus a unified estimation method is required. First, a single-port burner was experimentally evaluated using methane-hydrogen mixtures (hydrogen percentage: 0–50%vol, unburned mixture temperature:373–573K, equivalence ratio:0.8–2). Mathematical formulae of the critical boundary velocity gradient, which quantitatively depict the relationships between flashback, lifting and hydrogen percentage, temperature were provided. A multi-ports burner was subsequently assessed, and the results of the two burners showed good agreement. An analysis method for changes in the flame stability region and gas source replacement decision was proposed based on curves of the flashback and lifting limits. This work provides an important basis for introducing hydrogen into gas networks and the design and adjustment of gas appliances.     

Effects of heat treatment on the mechanical properties at elevated temperatures of plain-woven SiC/SiC composites

The effects of heat treatment on the mechanical properties of plain-woven SiC/SiC composites at 927 °C and 1200 °C in argon were evaluated through tensile tests at room temperature and at elevated temperature on the as-received and heat-treated plain-woven SiC/SiC composites, respectively. Heat treatment can improve the mechanical properties of composites at room temperature due to the release of thermal residual stress. Although heat treatment can damage the fiber, the effect of this damage on the mechanical properties of composites is generally less than the effect of thermal residual stress. Heat treatment will graphitize the pyrolytic carbon interface and reduce its shear strength. Testing temperature will affect the expansion or contraction of the components in the composites, thereby changing the stress state of the components. This study can provide guidance for the optimization of processing of ceramic matrix composites and the structural design in high-temperature environments.     

A compact cryogenic pump

A centrifugal cryogenic pump has been designed at Argonne National Laboratory to circulate liquid nitrogen (LN₂) in a closed circuit allowing the recovery of excess fluid. The pump can circulate LN₂ at rates of 2–10 L/min, into a head of 0.5–3 m. Over four years of laboratory use the pump has proven capable of operating continuously for 50–100 days without maintenance.     

Low shear rheological behaviour of two-phase mesophase pitch

The low shear rate rheology of two phase mesophase pitches derived from coal tar pitch has been investigated. Particulate quinoline insolubles (QI) stabilised the mesophase spheres against coalescence. Viscosity measurements over the range 10–10⁶ Pa s were made at appropriate temperature ranges. Increasing shear thinning behaviour was evident with increasing mesophase content. At low mesophase contents the dominant effect on the near Newtonian viscosity was temperature but at higher contents it was the shear rate; temperature dependence declined to near zero. The data indicated that agglomeration could be occurring at intermediate mesophase volume fractions, 0.2–0.3. The Krieger–Dougherty function and its emulsion analogue indicated that in this region the mesophase pitch emulsions actually behaved like ‘hard’ sphere systems and the effective volume fraction was estimated as a function of shear rate illustrating the change in extent of agglomeration. At the higher volume fractions approaching the maximum packing fraction, which could only be measured at higher temperatures, the shear thinning behaviour changed in character and it is considered that this is possibly due to shear induced deformation and breakup of dispersed drops in the shear field.